Poly[hemi-μ-aqua-[μ-2-(2-bromobenzenesulfonamido)benzoato]sodium(I)]

نویسندگان

  • Islam Ullah Khan
  • Muhammad Nadeem Arshad
  • Mehmet Akkurt
  • Ghulam Mustafa
  • Muhammad Shafiq
چکیده

The asymmetric unit of the title compound, [Na(C(13)H(9)BrNO(4)S)(H(2)O)(0.5)](n), contains two Na(+) cations, two substituted benzoate anions and one water molecule of crystallization. The Na(+) cations are coordinated in an octa-hedral geometry by two carboxyl-ate O atoms, two sulfonyl O atoms and two water O atoms. The latter two ligands occupy trans positions. The polymeric network structure of the title complex is characterized by a layered assembly parallel to (001) and is further consolidated by N-H⋯O, O-H⋯O and C-H⋯O hydrogen-bonding inter-actions.

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منابع مشابه

Poly[[tetra-μ2-aqua-diaqua-μ6-oxalato-barium(II)] 2,4,6-trinitro­phenolate monohydrate]. Corrigendum

In the paper by Hong, Song & Wu [Acta Cryst. (2007), E63, o2296], the scheme shows the wrong structure. The correct scheme is shown below and the compound name is corrected to "poly[[di-μ(2)-aqua-diaqua-hemi-μ(6)-oxalato-barium(II)] 2,4,6-trinitro-phenolate monohydrate", {[Ba(C(2)O(4))(0.5)(H(2)O)(4)]C(6)H(2)N(3)O(7)·H(2)O}(n).[This corrects the article DOI: 10.1107/S1600536807038159.].

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009